When released into the soil, this material may leach into gro undwater. Alvarado, u of michigan, 8206, 081910 the acquisition of nmr spectra in non deuterated solvents is not very different from regular acquisitions in deuterated solvents. P271 use only outdoors or in a wellventilated area. Alvarado, u of michigan, 8206, 081910 the acquisition of nmr spectra in non deuterated solvents is not very different from regular acquisitions in. Pdf effect of deuterated solvents on the excited state. Material safety data sheetmsds ethyl acetate synonyms. Repeated or extended contact may cause erythema reddening of the skin or dermatitis, resulting from a defatting action on tissue. Any release equal to or exceeding the rq must be reported to the national response center 8004248802 and appropriate state and local. Sec01 synonyms, trade names propanone, dimethyl ketone. Acetone d 6 is a deuterated nmr solvent useful in nmrbased research and analyses.
Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Supplier msds for updated copies of an msds, please contact anchem sales at the addressphone number on page 1 or fax the msds coordinator at 519 4514593. This msds has been prepared according to the hazard criteria of t he controlled products regulations cpr and the msds contains all of the information required by the cpr. Pyrolysis and photolysis of acetone d 6 and methane mixtures have been investigated as a function of temperature. Deuterated solvents acetone fisher scientific offers a broad range of high quality deuterated products from the acros organics and alfa aesar brands for all your routine synthesis and structural analysis needs. Deuterated ethanol is an uncommon solvent used in nmr spectroscopy. Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone. Inhalation of the vapour may result in drunkenness, see effects of swallowing above or headache, nausea, incoordination, narcosis sleepiness and vomiting.
Uses advised against no uses advised against are identified. Loosen clothing as necessary and position individual in a comfortable position. Pyrolysis and photolysis of acetoned 6 and methane mixtures have been investigated as a function of temperature. Avoid contact with dimethyl sulfoxide dmso solutions containing toxic materials or materials with. Identification of the substancemixture and of the companyundertaking 1. In this case, the base used is a deuterated version of lithium hydroxide. The most noticeable difference is that you wont be able to lock the magnet or to shim as. Firstaid measures general advice if symptoms persist, call a physician. Exposure to the spilled material may be irritating or harmful.
Handling and storage advice on general occupational hygiene conditions for safe storage, including any incompatibilities eating, drinking and smoking should be prohibited in areas where this material is. Msds for acetone page 5 of 7 msds 010 red text controlled copy grey text uncontrolled copy inhaled. Deuterated solvents for nmr spectroscopy in acroseal packaging. Deuterated ethanol c 2 d 5 od is a form called an isotopologue of ethanol c 2 h 5 oh in which the hydrogen atom h is replaced with deuterium heavy hydrogen isotope d. Safety data sheet ghs product identifier other means of identification product type section 1. We offer some of the most commonly used deuterated solvents in acroseal packaging. H336 euh066 no data available no data available not determined for full text of hstatements see section 16. Cas 67663 chloroform 100 % percentages are by weight section 4. Toxic by inhalation, in contact w ith skin and if swallowed. Astmd329 astm d329 acetone, technical grade o a51 page 2 of 6 reproductive toxiciity reproductive effects. Ammonium acetate safety data sheet according to federal register vol. None of the chemicals in this product are listed as hazardous substances under the cwa.
Barr 2105 channel avenue memphis, tn 381 emergency contact. Deuterated acetone cd 3 2 co, also known as acetoned 6, is a form called an isotopologue of acetone ch 3 2 co in which the hydrogen atom h is replaced with deuterium heavy hydrogen. First aid measures description of first aid measures after inhalation. Dimethyl sulfoxide page 2 of 5 cause liver and kidney damage. Overview, a wide range of magnisolv deuterated solvents with extremely low. Vwr international llc radnor corporate center building one suite 200. Deuterated acetone is prepared from heavy water, d 2 o, by what amounts to an aldol reaction. Accidental release measures personal precautions, protective equipment and emergency procedures. L of deuterated solvent and referenced to tms 0 ppm. Acetone, or propanone, is an organic compound with the formula ch32co. P280 wear eye protection, face protection, protective clothing, protective gloves. In the original publication, 1h nmr chemical shifts in d 2 o were reported relative to sodium 3trimethylsilylpropanesulfonate.
Acroseal packaging reduces the moisture uptake of the solvent compared to the regular packaging. If medical advice is needed, have product container or label at hand keep out of reach of children. In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Show this safety data sheet to the doctor in attendance. Safety data sheet according to 29cfr19101200 and ghs rev. Acetoned6 msds material safety data sheet or sds, coa and coq, dossiers, brochures and. L of deuterated solvent and were referenced to tms 0 ppm. Safety data sheet northwest missouri state university. International chemical safety card 0087 niosh pocket guide to chemical hazards acetone safety data sheet sds. Preexisting disorders involving any target organs mentioned in this msds as being at risk may be aggravated by overexposure to this product oshahcs status. Deuterated solvents for nmr nmr solvents nmr reference standards. Ensure that medical personnel are aware of the materials involved and take precautions to protect themselves. Identification of the substancemixture and of the companyundertaking.
Find msds or sds, a coa, data sheets and more information. Msds for acetone page 5 of 7 msds010 red text controlled copy grey text uncontrolled copy inhaled. The results clearly demonstrated the ability of the spinsolve benchtop nmrspectrometer to collect proton nmr spectra both in deuterated and nondeuterated solvents. Chemical product and company identification product name. Deuterated solvents for nmr spectroscopy in acroseal. Avoid contact with dimethyl sulfoxide dmso solutions containing toxic materials or materials with unknown toxicological properties. Skin absorption may cause toxic effects similar to those described for inhalation. Preexisting disorders involving any target organs mentioned in this msds as being at risk may be aggravated by overexposure to this product. Normalized excitation spectra of curcumin in deuterated chloroform, acetone, dimethyl sulfoxide and methanol. This material is considered hazardous by the osha hazard communication standard 29 cfr 1910. This material does not contain any class 1 ozone depletors. Acetone safety data sheet according to federal register vol. Extra dry solvents deuterated solvents organometallic.
Handling and storage advice on general occupational hygiene conditions for safe storage, including any incompatibilities eating, drinking and smoking should be prohibited in areas. Search results for deuterated acetone at sigmaaldrich. Accidental release measures personal precautions, protective. Vapour is moderately irritating to mucous membranes and respiratory. Methane is not listed in the iarc, ntp or by osha as a carcinogen or potential carcinogen. Methane is not listed in the iarc, ntp or by osha as a.
Vapour is moderately irritating to mucous membranes and respiratory tract. None of the chemicals in this product are listed as priority pollutants under the cwa. Safety data sheet acetone bdh1101 page 1 16 version 1. Accidental release measures contain spill and collect, as appropriate. This material is not known to cause any reproductive system damage.
Fisher scientific offers a broad range of high quality deuterated products from the acros organics and alfa aesar brands for all your routine synthesis and structural analysis. If inhaled if breathed in, move person into fresh air. Crown acetone 67641 2006622 95100 311,312 5000 company identity. In case of contact, flush skin with plenty of water. Regulatory information united states of america inventory component casno tsca tsca inventory notification activeinactive tsca epa regulatory flags acetone 67641 x active legend. This material does not contain any class 2 ozone depletors. Safety data sheet according to federal register vol.
Methane is inactive biologically and essentially nontoxic. Acetone revision date 25apr2019 unno un1090 proper shipping name acetone hazard class 3 packing group ii 15. When the acetone concentration is greater than 8% by weight in a closed container, it would be within the flammable range and cause fire or explosion if a source of ignition were introduced. Very toxic to aquatic life precautionary statements.